Dolly Parton's I Will Always Love You ranked first on a new special, CMT 40 Greatest Love Songs, which premiered on the network on Saturday (Feb. 12). 2 on the CMT list. 1 on the country chart in and also won a Grammy. “I Can't Help It (If I'm Still in Love With You),” Hank Williams (). There is one catch, however: Each artist can only have one song on this Top Country Love Songs list. That means well-known country. A list of what we feel are the best country love songs through the ages. You may or may Welcome to our entirely subjective list of the Top Most Romantic Country Love songs of all time. . 33) "I Can't Help It (If I'm Still In Love With You)" by Hank Williams 46) " I Will Always Love You " by Dolly Parton.